Atomic resolution images of solid-liquid interfaces

Adsorption of Proteins at Solid-Liquid Interfaces

This paper concisely rev iews the general principles underlying protein adsorption from aqueous so lution onto a solid surface. The discussion includes the various stages of the adsorption process, i. e., transport o f the protein molecules towards the su rface, the absorbed amount under equilibrium conditions, desorption andreadsorption. Among the interactions that determine the overall protei...

Potential-modulation spectroscopy at solid/liquid and liquid/liquid interfaces.

Potential-modulation spectroelectrochemical methods at solid/liquid and liquid/liquid interfaces are reviewed. After a brief summary of the basic features and advantages of the methods, practical applications of potential-modulation spectroscopy are demonstrated using our recent studies of solid/liquid and liquid/liquid interfaces, including reflection measurements for a redox protein on a modi...

Atomic-Scale Simulation Study of Equilibrium Solute Adsorption at Alloy Solid-Liquid Interfaces

Equilibrium structural properties of solid-liquid interfaces in Cu-Ni alloys are studied by Monte-Carlo simulations employing interatomic potentials based on the embedded-atom method. We describe a thermodynamicintegration approach used to derive bulk concentrations and densities for solid and liquid phases in two-phase thermodynamic equilibrium. These results are used as a basis for constructi...

Scanning Tunneling Microscopy at Solid-Liquid Interfaces

Electrostatic Potentials at Solid/Liquid Interfaces*

This review deals with electrostatic potentials within solid/electrolyte interfaces. The electrostatic potentials of several planes are defined and discussed: the inner surface potential affecting the state of charged surface species due to interactions with potential determining ions (Ψ0), the potential affecting the state of associated counterions (Ψβ), the potential at the onset of diffuse l...